User blog comment:AlmightyFreeman/Spider-Man Villains/@comment-25521424-20151215000215

Before the Sony-Marvel accord came out, i actualy thought about the idea of Dmitri Smerdyakov been the inventor of Photostatic Veil, a techology who would be later be confiscated by S.H.I.E.L.D. after its use for illegal pursuits. I would go with him, since he was the first supervillain Spidey fought in the comics.

I would really love to see Kraven, even if i don't think it could fit very well into an origin story. Scorpion would be cool too but i would like to avoid the recurring "villain copy-paste of the hero only more menacing" like Ant-Man/Yellow Jacket.