Hugo Weaving

Hugo Weaving portrayed Red Skull in Captain America: The First Avenger.

Trivia
Weaving has been in films with other actors from the Marvel Cinematic Universe before as the elf-lord Elrond in Peter Jackson's Lord of the Rings and Hobbit film series with Liv Tyler, Richard Armitage, Evangeline Lilly and Lee Pace. He was also V in the DC comics film, V For Vendetta, with Natalie Portman.